A. Galdikas et al., COPPER-DOPING LEVEL EFFECT ON SENSITIVITY AND SELECTIVITY OF TIN OXIDE THIN-FILM GAS SENSOR, Sensors and actuators. B, Chemical, 26(1-3), 1995, pp. 29-32
The influence of doping level of basic material on electrical resistan
ce controlled by gas chemisorption is investigated experimentally for
chemically deposited tin oxide thin films with different amounts of Cu
and Sb additives. Significant modification of dependences of resistan
ce versus temperature in oxygen-rich atmosphere and anomalous change o
f selectivity of resistance response to CO and H-2 gas are obtained by
different doping levels of the films. The main features of the experi
mental results are explained by the variation of the position of the F
ermi level with the concentration of bulk impurities.