Fl. Dickert et al., SUPRAMOLECULAR RECEPTORS FOR SAW AND QMB DEVICES - SOLVENT RECOGNITION EVALUATED BY FT-IR SPECTROSCOPY AND BET ADSORPTION ANALYSIS, Sensors and actuators. B, Chemical, 26(1-3), 1995, pp. 199-202
Sensor effects can be predicted by force field calculations if the for
mation of host-guest complexes determines the sensor signal. Strong su
pport for this supramolecular recognition is available by BET analysis
. This method allows the determination of the number of strong complex
ing sites in the layer and the corresponding heats of adsorption that
are in good agreement with calculated data. Additionally, the host-gue
st interaction can be pursued by FT-IR spectroscopy using CDCl3 as sen
sitive probe. These ideas can be used to design rugged functionalized
polymeric sensor materials that fulfill the requirements of practical
sensoric operation.