Gp. Crawford et al., CONSTRAINED LIQUID-CRYSTALS AND POLYMER NETWORKS - A TEXTURE STUDY OFELASTICITY AND ORDERING, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 251, 1994, pp. 265
Nematic liquid crystals confined to cylindrical cavities, and polymer
networks constrained by the presence of an oriented liquid crystal are
studied. Frank elastic theory is used to predict stable nematic struc
tures and to calculate their corresponding interference patterns (text
ures) for structures observed with a polarizing microscope. The compar
ison of theoretical and experimental textures are used to investigate
nematic ordering which result in the measurement of the bend-to-splay
(K-33/K-11) bulk elastic constant ratio, the saddle-splay-to-splay (K-
24/K-11) surface elastic constant ratio, and the degree of orientation
al order of polymer networks induced by the nematic liquid crystal dur
ing the formation of these networks.