Th. Zhang et al., INFLUENCE OF THE STRUCTURE OF IMPLANTED STEEL WITH Y, Y-RESISTANCE(C AND Y+CR ON THE BEHAVIORS OF WEAR, OXIDATION AND CORROSION), Surface & coatings technology, 72(1-2), 1995, pp. 93-98
New methods were studied to improve the properties of corrosion, wear
and oxidation resistance of implanted H13 steel using ions of Y, Cr, Y
+ C and Y + Cr, produced by a pulsed metal ion source (MEVVA). The re
sults show that the behaviors of wear, corrosion and oxidation resista
nce were improved obviously for four kinds of ion implantation into H1
3 steel. The oxidation resistance of single Y implantation at 25 mu A
cm(-2) is better than at higher fluxes. The wear and oxidation resista
nce of Y + C are better than those of Cr, Y and Y + Cr implantation. T
he corrosion resistance of high dose implantation is better than that
of low dose implantation. The structural changes of the implanted laye
r before and after oxidation were measured by X-ray diffraction. An im
provement in the above-mentioned properties is closely related to the
structural change of yttrium-iron alloy and yttrium-iron oxidation com
pounds. The compounds were formed during a short-time (10 min) oxidati
on. Because of the compound formation, a strong Y atom concentration p
rofile appeared. The shape of the profile is constant during oxidation
at 800 degrees C for 40 min. Finally, the mechanism of influence of t
he oxidation compounds and the strange shape of the profile on the pro
perties of the implanted layer is discussed.