CATALYTIC ORGANIC-SOLID GAS REACTION - KINETIC AND MECHANISM

Authors
SELATNIA A BASSUS J LAMARTINE R DUCHAMP C
Citation
A. Selatnia et al., CATALYTIC ORGANIC-SOLID GAS REACTION - KINETIC AND MECHANISM, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 248, 1994, pp. 71-79
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
248
Year of publication
1994
Pages
71 - 79
Database
ISI
SICI code
1058-725X(1994)248:<71:COGR-K>2.0.ZU;2-2
Abstract
The alkylation of solid 4-tertiobutylphenol by gaseous isobutene in th e presence of a catalyst has been studied according to different param eters such as, temperature, initial pressure of isobutene, proportion of catalyst and the granulometry of the catalyst and the solid reactan t. Among the predefined kinetic models, the unreacted core model for S pherical particles of unchanging size is the best adapted to the exper imental results. Based on this model, a mechanism is proposed involvin g the intervention of a carbocation.