P. Mansky et al., MONOLAYER FILMS OF DIBLOCK COPOLYMER MICRODOMAINS FOR NANOLITHOGRAPHIC APPLICATIONS, Journal of Materials Science, 30(8), 1995, pp. 1987-1992
Several techniques have been investigated for creating large-area thin
films of diblock copolymers, with well-ordered two-dimensional period
ic microstructure on the scale of a few tens of nanometres. Such struc
tures might potentially be used as templates for lithography, at a len
gth scale not easily accessed by electron-beam methods. Using a copoly
mer with a spherical microdomain structure, we find that it is quite e
asy to obtain large-area films consisting of a monolayer of spherical
domains, arranged on a hexagonal lattice with a lattice constant of 33
nm. Copolymers with cylindrical microstructure typically orient paral
lel to the substrate and free surface, it has been found that the perp
endicular orientation is metastable: if a well- or poorly-ordered film
is initially prepared with the cylinders perpendicular to the surface
, annealing results in a well-ordered film with the same orientation,
with a lattice constant of 27 nm for the polymer used in this study. F
or both cylinders and spheres, grains measuring typically 30 x 30 latt
ice constants are readily obtained.