GEOMETRIC CONTROL OF SELECTIVITY IN ALKALI-METAL ION COMPLEXATION BY ACYCLIC N-4-TRIPODAL LIGANDS

Authors
CHUANG CL FRID M CANARY JW
Citation
Cl. Chuang et al., GEOMETRIC CONTROL OF SELECTIVITY IN ALKALI-METAL ION COMPLEXATION BY ACYCLIC N-4-TRIPODAL LIGANDS, Tetrahedron letters, 36(17), 1995, pp. 2909-2912
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
17
Year of publication
1995
Pages
2909 - 2912
Database
ISI
SICI code
0040-4039(1995)36:17<2909:GCOSIA>2.0.ZU;2-4
Abstract
A simple mass spectrometry experiment established that two acyclic N-4 -tripodal ligands bind lithium ion with surprisingly high selectivity in a methanol/ water solution of five alkali metal perchlorate salts. The selectivity was confirmed by a H-1 NMR experiment.