SPONGIAN FURANODITERPENES - AN INTRAMOLECULAR RADICAL APPROACH

Citation
Pa. Zoretic et al., SPONGIAN FURANODITERPENES - AN INTRAMOLECULAR RADICAL APPROACH, Tetrahedron letters, 36(17), 1995, pp. 2929-2932
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
17
Year of publication
1995
Pages
2929 - 2932
Database
ISI
SICI code
0040-4039(1995)36:17<2929:SF-AIR>2.0.ZU;2-5
Abstract
An oxidative free-radical cyclization of polyene 3, derived from farne syl acetate,has been utilized in the construction of 4 containing six chiral centers. The direct conversion of 4 to the intact spongian skel eton 9 is also reported.