EFFICIENT DESYMMETRIZATION OF 1,2-DIOL AND 1,3-DIOL BY DIMETHYLDIOXIRANE

Citation
P. Bovicelli et al., EFFICIENT DESYMMETRIZATION OF 1,2-DIOL AND 1,3-DIOL BY DIMETHYLDIOXIRANE, Tetrahedron letters, 36(17), 1995, pp. 3031-3034
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
17
Year of publication
1995
Pages
3031 - 3034
Database
ISI
SICI code
0040-4039(1995)36:17<3031:EDO1A1>2.0.ZU;2-D
Abstract
Dimethyldioxirane was used to monooxidize 1,2 and 1,3 sec,sec-diols to the corresponding ketoalcohols, exploiting the inhibiting effect of t he formed carbonyl group on the course of the process.