A new attractive polycondensation provides cross-linked solvating poly
ethers. The electrolytes prepared from these networks exhibit good ion
ic conductivities from ambient temperature. Their thermal and electroc
hemical behaviour allow their use in lithium batteries. A comparison b
etween the conductivities of lithium, sodium and potassium network ele
ctrolytes shows that lithium electrolytes are more conductive at high
concentration while for O/M>20 potassium electrolytes exhibits the bes
t conductivity.