Mt. Santos et al., THE INFLUENCE OF THERMAL-TREATMENT IN OXI-REDUCTIVE ENVIRONMENTS ON THE SURFACE OF BI4GE3O12, BI12GEO20 AND BI12SIO20 SINGLE-CRYSTALS, Materials research bulletin, 30(5), 1995, pp. 631-635
Thermal treatments at temperatures ranging from 400 to 800 degrees C w
ere performed on single crystal samples of Bi4Ge3O12, Bi12GeO20 and Bi
12SiO20, in N-2-H-2 and O-2-water vapor atmospheres. The H+ content of
the samples remained unchanged after the treatments. These treatments
lead to surface reduction which is analyzed by electron microprobe.