Experimental investigations were carried out in order to evaluate the
substrate permeability of starch and its microbial metabolites, using
the pellets of Aspergillus niger formed by 5-d culture. The distributi
on coefficients were almost constant irrespective of the initial total
organic carbon (TOC) concentration, but decreased slightly with incre
ase in the pellet diameter. This trend was negligible for substrates o
ther than soluble starch and their average distribution coefficients w
ere almost unity. The apparent intra-pellet diffusion coefficients of
these substrates and oxygen increased with increase in the pellet diam
eter, and were almost identical for the same diameter of pellet regard
less of the substrate. It was suggested that mass transfer flow rate o
f substrate appeared to be higher because of a sparser structure and a
lower density with larger diameter of pellets formed by 5-d culture.