H. Shirakawa et al., SYNTHESIS OF LIQUID-CRYSTALLINE POLYACETYLENE DERIVATIVES, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 255, 1994, pp. 213-219
Mono-substituted acetylenes with liquid crystalline group consisting o
f phenylcyclohexyl and biphenyl moieties as mesogenic cores have been
synthesized and polymerized using Ziegler-Natta and metathesis catalys
ts. Measurements of DSC and polarized microscopy showed that the polym
ers have smectic liquid crystal phases, while the monomer with phenylc
yclohexyl moiety linked with octyl terminal group has nematic phase.