Ch. Lee et al., THE EFFECT OF OXYGEN ON THE PHOTOCONDUCTIVITY OF C-60 FILM - ACTION SPECTRUM AND TEMPERATURE-DEPENDENCE, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 256, 1994, pp. 769-774
We report the effect of oxygen on the action spectrum of the steady-st
ate photoconductivity (PC) of C-60 film and its temperature dependence
. The steady-state PC decreases more than 4 orders of magnitude upon e
xposure to oxygen; the PC decreases faster below HBAR omega approximat
e to 2.3 eV. The low-temperature PC spectrum of the oxygen-free C-60 i
s similar to the high-temperature PC spectrum of C-60 exposed to oxyge
n. The steady-state PC exhibits a peak at T approximate to 240 K in th
e oxygen-free C-60, which disappears in C-60 exposed to oxygen. The re
sults indicate that the oxygen in C-60 film acts as an efficient deep
trap for photoexcited carriers and reduces the structural order.