THE EFFECT OF OXYGEN ON THE PHOTOCONDUCTIVITY OF C-60 FILM - ACTION SPECTRUM AND TEMPERATURE-DEPENDENCE

Citation
Ch. Lee et al., THE EFFECT OF OXYGEN ON THE PHOTOCONDUCTIVITY OF C-60 FILM - ACTION SPECTRUM AND TEMPERATURE-DEPENDENCE, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 256, 1994, pp. 769-774
Citations number
15
Categorie Soggetti
Crystallography
ISSN journal
1058725X
Volume
256
Year of publication
1994
Pages
769 - 774
Database
ISI
SICI code
1058-725X(1994)256:<769:TEOOOT>2.0.ZU;2-G
Abstract
We report the effect of oxygen on the action spectrum of the steady-st ate photoconductivity (PC) of C-60 film and its temperature dependence . The steady-state PC decreases more than 4 orders of magnitude upon e xposure to oxygen; the PC decreases faster below HBAR omega approximat e to 2.3 eV. The low-temperature PC spectrum of the oxygen-free C-60 i s similar to the high-temperature PC spectrum of C-60 exposed to oxyge n. The steady-state PC exhibits a peak at T approximate to 240 K in th e oxygen-free C-60, which disappears in C-60 exposed to oxygen. The re sults indicate that the oxygen in C-60 film acts as an efficient deep trap for photoexcited carriers and reduces the structural order.