This study focuses on the molecular fragmentation of starch as a resul
t of extrusion-based thermomechanical processing. Gel permeation chrom
atography-light scattering and bulk intrinsic viscosity measurements w
ere used for the macromolecular characterization. The data indicate th
at the extrusion processing of starch results in a reduction in its mo
lecular weight. Such a fragmentation of the starch polymer could be at
tributed, at least partly, to debranching of the molecules.