PHOTOINDUCED HOLE AND ELECTRON-TRANSFER FROM POLY(PHENYLENE VINYLENE)INTO MOLECULARLY DOPED POLYMERS

Authors
ABKOWITZ MA ANTONIADIS H FACCI JS JENEKHE SA HSIEH BR STOLKA M
Citation
Ma. Abkowitz et al., PHOTOINDUCED HOLE AND ELECTRON-TRANSFER FROM POLY(PHENYLENE VINYLENE)INTO MOLECULARLY DOPED POLYMERS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 252, 1994, pp. 1-10
Citations number
22
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
252
Year of publication
1994
Pages
1 - 10
Database
ISI
SICI code
1058-725X(1994)252:<1:PHAEFP>2.0.ZU;2-A
Abstract
Photoinduced hole transfer between photoexcited x-conjugated polymer, poly(p-phenylene vinylene) (PPV) and an adjacent trap-free hole-transp ort molecularly doped polymer containing TPD in a polycarbonate binder in an electric field, is analyzed. Also analyzed and described, under similar electric field conditions, is photoinduced electron transfer between PPV and a trap-free electron transport polymer containing BCFM and a polycarbonate binder. Transfer of carriers, both holes and elec trons, to the respective transport layers is fast and coherent, withou t delay. The collection efficiency at an electric field of 4x10(5)Vcm( -1) is 25% for photoinduced holes and near 0.2% for photoinduced elect rons.