T. Hiraga et al., CONDENSED STATES AND OPTICAL-PROPERTIES OF THE DENSELY DISSOLVED ORGANIC-COMPOUNDS IN POLYMER MATRICES BY COPRECIPITATION, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 252, 1994, pp. 185-193
Association of 3,3'-Diethyloxadicarbocyanine Iodide (DODCI) molecules
has been revealed in polymer matrices [poly(methyl methacrylate), poly
(benzyl methacrylate), etc.], comparing it with association states in
appropriate solvents ranging from a dilute concentration (similar to 1
0(-5) mol/l) to one, and in a crystal grown in methanol. The associati
on state was investigate by means of optical-absorption and emission s
pectroscopy, emission lifetime analysis, C-13-NMR spectroscopy and sma
ll angle X-ray scattering. Properties of DODCI molecules in polymer ma
trices were controlled by varying side-chain substituents of the polym
ers, and DODCI contents.