L. Kador et P. Geissinger, ANALYTICAL DESCRIPTION OF EXTERNAL-FIELD EFFECTS ON PERSISTENT-HOLE SPECTRA IN DISORDERED MATERIALS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 252, 1994, pp. 213-221
External-field effects on persistent-hole spectra in disordered solids
can be described with a stochastic theory of dye-matrix interaction.
For obtaining analytical results, usually two approximations are perfo
rmed in the calculation, the continuum approximation which is valid fo
r sufficiently low matrix densities, and the Gaussian approximation wh
ich is valid for high densities. Hence, the validity range of the resu
lts is not clear a priori. The paper shows for the special case of pre
ssure tuning that both approximations must be relaxed in a proper desc
ription of the physical situation. Especially the continuum approximat
ion which consists in neglecting any correlations between the matrix m
olecules, leads to quantitatively incorrect results.