S. Koshihara et al., DYNAMICS OF PHOTOINDUCED PHASE-TRANSITION IN LOW-DIMENSIONAL ORGANIC-CRYSTALS AND THE ROLE OF PHOTOCARRIERS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 252, 1994, pp. 283-292
We report the dynamics of a unique photo-induced phenomenon in quasi-o
ne-dimensional organic crystals; i.e. phase transitions triggered by p
hoto-excitation in conjugated polymers and charge-transfer crystals. N
ano-second and pico-second time-resolved studies indicate that photo-g
enerated charge-carriers (bi-polarons) play an important role in the d
riving process of the photo-induced phase transition (PIPT).