We employed a radical beam assisted deposition technique to prepare si
ngle-crystal niobium nitride thin films on MgO(100) substrates. The ra
dical beam containing excited species of nitrogen was produced by an e
lectron cyclotron resonance plasma source and used to irradiate the gr
owing Nb film which was deposited simultaneously by an electron-gun va
pour source. The nitride film was found to grow epitaxially on the sub
strate heated to 600-650 degrees C. The resulting NbN film formed had
predominantly B1 structure, resistivity of 44 mu Omega cm at 20 K, and
almost equiatomic composition.