Citation
Y. Ozawa et K. Toriumi, ELECTROCHEMICAL SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL ONE-DIMENSIONAL HALOGEN-BRIDGED NICKEL(III) COMPLEX, Chemistry Letters, (4), 1995, pp. 257-258
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ISSN journal
03667022
Issue
4
Year of publication
1995
Pages
257 - 258
Database
ISI
SICI code
0366-7022(1995):4<257:ESACOA>2.0.ZU;2-L
Abstract
A novel halogen-bridged one-dimensional Ni-III-X-Ni-III compound, {[Ni
-III(en)(2)Cl]Cl-2}infinity) (en = C2H8N2) has been synthesized by ele
ctrochemical oxidation. Single crystal X-ray crystallography revealed
that a bridging halogen ion is located on the midpoint between two Ni(
III) atoms with Ni-Cl 2.438 (1) Angstrom. This is the first example fo
r electrocrystallization of halogen-bridged 1-D metal complexes.