SYNTHESIS OF HIGHER-NUCLEARITY CLUSTERS BY USE OF SMALL CLUSTER UNITSAS BUILDING-BLOCKS - SYNTHESIS AND X-RAY STRUCTURE-ANALYSIS OF [CLCCO3(CO)(8)](2)(MU-DPPE) AND [CLCCO3(CO)(7)][CLCCO3(CO)(8)](MU-TRIPHOS) (DPPE=1,2-BIS(DIPHENYLPHOSPHINO)ETHANE PHOS=BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE)

Authors
ONAKA S OTSUKA M
Citation
S. Onaka et M. Otsuka, SYNTHESIS OF HIGHER-NUCLEARITY CLUSTERS BY USE OF SMALL CLUSTER UNITSAS BUILDING-BLOCKS - SYNTHESIS AND X-RAY STRUCTURE-ANALYSIS OF [CLCCO3(CO)(8)](2)(MU-DPPE) AND [CLCCO3(CO)(7)][CLCCO3(CO)(8)](MU-TRIPHOS) (DPPE=1,2-BIS(DIPHENYLPHOSPHINO)ETHANE PHOS=BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE), Chemistry Letters, (4), 1995, pp. 269-270
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1995
Pages
269 - 270
Database
ISI
SICI code
0366-7022(1995):4<269:SOHCBU>2.0.ZU;2-Y
Abstract
Two ClCCo3(CO)(9) units are, after treatment with Me(3)NO, linked at b asal, cobalt atoms by dppe spacer to yield [ClCCo3(CO)(8)](2)(mu-dppe) and by TRIPHOS to yield [ClCCo3(CO)(7)][ClCCo3(CO)(8)](mu-TRIPHOS); t hey are characterized by single crystal X-ray molecular structure anal ysis and two Cl atoms in the TRIPHOS derivative are found to be locate d in close proximity.