A NOVEL CONVERSION OF 3,7-DISUBSTITUTED 2H,6H-TETRAHYDRO-1,5,3,7-DISELENADIAZOCINES TO 4-SUBSTITUTED 1,2,4-DISELENAZOLIDINES BY TREATING WITH OXIDIZING-AGENTS

Authors
TAKIKAWA Y KOYAMA Y YOSHIDA T SHIMADA K KABUTO C
Citation
Y. Takikawa et al., A NOVEL CONVERSION OF 3,7-DISUBSTITUTED 2H,6H-TETRAHYDRO-1,5,3,7-DISELENADIAZOCINES TO 4-SUBSTITUTED 1,2,4-DISELENAZOLIDINES BY TREATING WITH OXIDIZING-AGENTS, Chemistry Letters, (4), 1995, pp. 277-278
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1995
Pages
277 - 278
Database
ISI
SICI code
0366-7022(1995):4<277:ANCO32>2.0.ZU;2-4
Abstract
Oxidation of 3,7-disubstituted 2H,6H-tetrahydro-1,5,3,7-diselenadiazoc ines afforded 4-substituted 1,2,4-diselenazolidines in modest yields. The intermediates of the reactions were supposed to be diselena dicati ons possessing 1,5,3,7-diselenadiazabicyclo[3.3.0]octane skeleton gene rated transiently by the transannular interaction of two selenium atom s.