STEREOSELECTIVE ALLYLATION OF BETA-HYDROXY-ALPHA,BETA-ENONES AND BETA-AMINO-ALPHA,BETA-ENONES WITH ALLYLTRIFLUOROSILANE TRIETHYLAMINE SYSTEMS

Authors
KIRA M SATO K SEKIMOTO K GEWALD R SAKURAI H
Citation
M. Kira et al., STEREOSELECTIVE ALLYLATION OF BETA-HYDROXY-ALPHA,BETA-ENONES AND BETA-AMINO-ALPHA,BETA-ENONES WITH ALLYLTRIFLUOROSILANE TRIETHYLAMINE SYSTEMS, Chemistry Letters, (4), 1995, pp. 281-282
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1995
Pages
281 - 282
Database
ISI
SICI code
0366-7022(1995):4<281:SAOBAB>2.0.ZU;2-L
Abstract
Reactions of allyltrifluorosilanes with beta-functional-alpha,beta-eno nes such as o-hydroxy- and o-aminophenyl ketones and 1,3-diketones in the presence of triethylamine yielded the corresponding tertiary homoa llyl alcohols in regiospecific and highly diastereoselective manner.