FORMAL HYDROALLYLATION OF CARBON-CARBON TRIPLE BONDS VIA TANTALUM-ALKYNE COMPLEXES - STEREOSELECTIVE PREPARATION OF 1,4-DIENES

Authors
TAKAI K YAMADA M ODAKA H UTIMOTO K FUJII T FURUKAWA I
Citation
K. Takai et al., FORMAL HYDROALLYLATION OF CARBON-CARBON TRIPLE BONDS VIA TANTALUM-ALKYNE COMPLEXES - STEREOSELECTIVE PREPARATION OF 1,4-DIENES, Chemistry Letters, (4), 1995, pp. 315-316
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1995
Pages
315 - 316
Database
ISI
SICI code
0366-7022(1995):4<315:FHOCTB>2.0.ZU;2-7
Abstract
Treatment of tantalum-alkyne complexes with lithium salts of allylic a lcohols in DME-benzene-THF (1:1:1) at 25 degrees C for several hours g ives 1,4-dienes stereoselectively in good to excellent yields.