ASYMMETRIC ALLYLIC ALKYLATION CATALYZED BY PALLADIUM COMPLEXES WITH ANEW CHIRAL BISPHOSPHINE LIGAND

Authors
LONGMIRE JM ZHU GX ZHANG XM
Citation
Jm. Longmire et al., ASYMMETRIC ALLYLIC ALKYLATION CATALYZED BY PALLADIUM COMPLEXES WITH ANEW CHIRAL BISPHOSPHINE LIGAND, Tetrahedron letters, 38(3), 1997, pp. 375-378
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
3
Year of publication
1997
Pages
375 - 378
Database
ISI
SICI code
0040-4039(1997)38:3<375:AAACBP>2.0.ZU;2-B
Abstract
A novel, chiral bisphosphine ligand has been synthesized and its palla dium complexes have been used in asymmetric allylic alkylation. High r eactivity and moderate selectivity have been realized in the reaction between 1,3-diphenyl-2-propenyl acetate and dimethyl malonate. Copyrig ht (C) 1996 Elsevier Science Ltd