Nonlinear optical transmission in unintentionally or lightly doped CdS
crystals is studied theoretically and experimentally near the band ga
p. A spatially homogeneous three-level model is developed which explai
ns the observed optical switching process and its dependence upon inci
dent intensity, wavelength, lattice temperature, and surface reflectiv
ity. It is shown that the switching is due to the dynamics of the gene
ration-recombination processes involving donors, accepters, and the co
nduction band: and not due to transmissive optical bistability.