HIGH-PRESSURE CONDUCTIVITY STUDY OF TEMPLATE SYNTHESIZED POLYPYRROLE - OBSERVATION OF A CROSSOVER FROM 3-DIMENSIONAL TO ONE-DIMENSIONAL VARIABLE-RANGE-HOPPING
B. Lorenz et al., HIGH-PRESSURE CONDUCTIVITY STUDY OF TEMPLATE SYNTHESIZED POLYPYRROLE - OBSERVATION OF A CROSSOVER FROM 3-DIMENSIONAL TO ONE-DIMENSIONAL VARIABLE-RANGE-HOPPING, Philosophical magazine. B. Physics of condensed matter. Structural, electronic, optical and magnetic properties, 71(5), 1995, pp. 929-940
We have studied thin films of thin and thick wall template synthesized
polypyrrole microtubules. We observe a crossover from three- to one-d
imensional variable range hopping in our samples at low temperatures.
Our results clearly indicate that the geometry of the microtubules has
an influence on the conductivity. The transition temperature from thr
ee- to one-dimensional Variable range hopping shifts to lower temperat
ures when high pressure is applied. The results are discussed on the b
asis of the geometry of the microtubules.