Buoyancy-induced flow (BIF) of both O-18-enriched (delta(18)O, +160 to
+5195 parts per thousand) and O-18-depleted (delta(18)O, -500 parts p
er thousand) water has been studied in a 10-cm-diameter tube that simu
lates a section of a well. BIF was detected in all the experiments for
a density contrast (Delta rho) between 0.03 and 1.0 sigma units (equi
valent to a total dissolved solids contrast of 30-1000 mg/L). The magn
itude of the Rayleigh number suggests that the natural convection flow
is turbulent. A mathematical model is presented to predict vertical t
racer propagation inside the cavity. The model assumes a local mixing
length scale proportional to the tube diameter. A possible transition
to the laminar natural convection regime, with a significant reduction
in mixing rate compared to that predicted by the model, is detected w
hen the density contrast is reduced to Delta rho = 0.03 sigma units. T
his smaller mixing rate is still orders of magnitude larger than diffu
sion alone. BIF may be an important groundwater transport and mixing m
echanism in open conduits in aquifers. Its effects should also be cons
idered when performing tracer experiments in the field.