Storm flow in forested basins on the Canadian Shield is largely suppli
ed by subsurface water; however, mechanisms by which this water reache
s the stream remain unclear. Side slope contributions to storm flow we
re studied using throughflow trenches on slopes in a headwater basin n
ear Dorset, Ontario. Discharge, soil water content, and chemical and i
sotopic signatures of subsurface water were monitored at each site. Fo
ur hypotheses were tested: (1) most flow occurs at the soil-bedrock in
terface on shield slopes with thin soil; (2) a significant fraction of
event water moves vertically to bedrock via preferential flow pathway
s and laterally over the bedrock surface; (3) relative preevent water
contribution to subsurface flow on shield slopes is a function of soil
thickness; and (4) a significant portion of event water flux in storm
flow from forested basins with shallow soil cover is supplied from si
de slopes via subsurface flow along the soil-bedrock interface. Hypoth
esis 1 was confirmed from hydrometric observations during spring and f
all rainstorms. Hypotheses 2 and 3 were supported by temporal trends i
n dissolved organic carbon and O-18 in flow at the soil-bedrock interf
ace and by isotopic hydrograph separations (IHSs) of hillslope runoff.
Comparison with the streamflow IHS indicated that event water flux fr
om the basin in excess of that attributable to direct precipitation on
to near-channel saturated areas could be supplied by flow along the be
drock surface (hypothesis 4). Flow at the soil-bedrock interface on si
de slopes also contributed similar to 25% of preevent water flux from
the basin. Much of the event water component of basin storm flow may t
ravel considerable distances via subsurface routes and is not necessar
ily contributed by surface runoff processes (Horton flow or saturation
overland flow). Therefore the assumption that event water undergoes l
ittle interaction with the soil during its passage downslope may be un
warranted here.