STUDIES ON M-CYCLOPHANE FORMATION FROM THE PHOTOLYSIS OF CHLOROACETAMIDE DERIVATIVES

Authors
REZAIE R BREMNER JB BLANCH GK SKELTON BW WHITE AH
Citation
R. Rezaie et al., STUDIES ON M-CYCLOPHANE FORMATION FROM THE PHOTOLYSIS OF CHLOROACETAMIDE DERIVATIVES, Heterocycles, 41(5), 1995, pp. 959-972
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
41
Issue
5
Year of publication
1995
Pages
959 - 972
Database
ISI
SICI code
0385-5414(1995)41:5<959:SOMFFT>2.0.ZU;2-5
Abstract
The synthesis of 6-azabicyclo[7.3.1.]trideca-1(13),9,11-trien-5-one (4 ) is described. Two routes to (4) based on the photolysis of N-[2-(3,4 -dimethoxyphenyl)ethyl]chloroacetamide (2b) and methylsiloxy-3-methoxy phenyl)ethyl]chloroacetamide (2c) followed by O-demethylation or O-des ilylation, were developed. Extension of the work has given the new m-c yclophane ester derivative (9), whose structure has been confirmed by X-ray crystallography.