CHARACTERIZATION AND CATALYTIC PROPERTIES OF ZEOLITE MCM-22

Citation
R. Ravishankar et al., CHARACTERIZATION AND CATALYTIC PROPERTIES OF ZEOLITE MCM-22, Microporous materials, 4(1), 1995, pp. 83-93
Citations number
30
Categorie Soggetti
Chemistry Physical","Material Science","Chemistry Applied
Journal title
ISSN journal
09276513
Volume
4
Issue
1
Year of publication
1995
Pages
83 - 93
Database
ISI
SICI code
0927-6513(1995)4:1<83:CACPOZ>2.0.ZU;2-0
Abstract
Characterization of MCM-22 was carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal analysis (TGA-DTA) and nu clear magnetic resonance (NMR). TGA-DTA and NMR studies indicate a str ong interaction of the template with the zeolite framework. Adsorption studies indicate the internal void volume to be intermediate between the volumes of zeolite beta and ZSM-12. In catalytic reactions such as the isomerization of m-xylene, aromatization of n-hexane and transfor mation of methanol to hydrocarbons, the zeolite behaves like a large-p ore zeolite, even though recent research has established that it is a medium-pore zeolite.