FAR-INFRARED TRANSMITTANCE OF SC-2-AT-C-84 AND ER-2-AT-C-82

Citation
Sm. Grannan et al., FAR-INFRARED TRANSMITTANCE OF SC-2-AT-C-84 AND ER-2-AT-C-82, Chemical physics letters, 264(3-4), 1997, pp. 359-365
Citations number
26
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
264
Issue
3-4
Year of publication
1997
Pages
359 - 365
Database
ISI
SICI code
0009-2614(1997)264:3-4<359:FTOSAE>2.0.ZU;2-W
Abstract
We have measured the far infrared transmittance of Sc-2@C-84 and Er-2@ C-82 at 1.5 K between 30 and 200 cm(-1). Both materials are observed t o have a large primary absorption feature centered at 95 cm(-1) with a width of approximately 50 cm(-1), as well as a number of secondary ab sorption features which are different in the two materials, This is th e first study of the far infrared properties of metallofullerenes and may help in the determination of the structural and electronic propert ies of these materials.