THE TRIS(TELLURATO)MANGANATE(IV) ANION - SPECTROSCOPIC AND STRUCTURALSTUDIES OF NA7K [MN(TEO4(OH)(2))(3)]CENTER-DOT-3H(2)O

Authors
LEVASON W OLDROYD RD
Citation
W. Levason et Rd. Oldroyd, THE TRIS(TELLURATO)MANGANATE(IV) ANION - SPECTROSCOPIC AND STRUCTURALSTUDIES OF NA7K [MN(TEO4(OH)(2))(3)]CENTER-DOT-3H(2)O, Polyhedron, 14(8), 1995, pp. 967-970
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
8
Year of publication
1995
Pages
967 - 970
Database
ISI
SICI code
0277-5387(1995)14:8<967:TTA-SA>2.0.ZU;2-X
Abstract
The deep red manganese(IV) complex Na7K[Mn{TeO4(OH)(2)}(3)]. 3H(2)O ha s been prepared by S2O82- oxidation of a mixture of manganese(II) salt and telluric acid in aqueous alkali. It has been characterized by ana lysis, IR and UV-vis spectroscopy and magnetic measurements. The struc ture of the anion has been established by a combination of manganese a nd tellurium K-edge EXAFS studies. Attempts to obtain a nickel(IV) tel lurate have been unsuccessful.