Crop residues left in the field after harvest can be important in cont
rolling soil erosion. Current methods for quantifying percent crop res
idue cover are tedious and somewhat subjective. There is a need for ne
w methods to quantify residue cover that are rapid, accurate, and obje
ctive. We evaluated reflectance and fluorescence techniques for discri
minating crop residues from a wide range of soils. Reflectance and flu
orescence spectra of 37 agricultural soils (wet and dry) and of recent
ly harvested and weathered corn (Zea mays L.), soybean [Glycine mar (L
.) Mere], sorghum [Sorghum bicolor (L.) Moench], and wheat (Triticum a
estivum L.) residues were measured in the lab. Reflectance factors in
the visible or near-infrared wavelengths did not uniquely distinguish
all soils from all crop residues. Crop residues may be brighter or dar
ker than a given soil, depending on soil moisture and residue age. Whe
n illuminated with ultraviolet radiation, however, the crop residues f
luoresced more than most of the soils. Fluorescence of crop residues w
as a broad-band phenomenon centered between 420 to 520 nm and induced
by a relatively broad range of excitation wavelengths centered between
350 to 400 nm. More than 90% of the crop residues <2 yr old could be
discriminated from 33 of 37 dry soils and 36 of 37 wet soils using flu
orescence. The threshold for discrimination can be optimized for class
ification accuracy for each soil. Fluorescence techniques are less amb
iguous than reflectance methods and are better suited for discriminati
ng crop residues on soils. Furthermore, if properly implemented, fluor
escence techniques can be used to quantify crop residue cover in the f
ield.