I. Dahl et A. Demeyere, ON HIGHER-ORDER VARIATIONAL ANALYSIS IN ONE-DIMENSIONS AND 3-DIMENSIONS FOR SOFT BOUNDARIES, Liquid crystals, 18(5), 1995, pp. 683-692
For some problems in liquid crystal physics we need to use the Euler e
quation and the corresponding boundary equation in the three-dimension
al case with soft boundaries. As a further complication the free energ
y expression, which should be minimized, might contain some second-ord
er and third-order derivatives. These higher-order derivatives will ca
use the spatial derivatives of the boundary normal to appear in the bo
undary equation. Explicit formulae are given for the Euler equation an
d the corresponding surface equations for a general case. As an exampl
e, the theory is applied to nematic liquid crystals, where the general
Euler equations and surface molecular fields are derived, including t
he effects of an imposed electric field.