PHOTOADDUCT BETWEEN TRIS(1,4,5,8-TETRAAZAPHENANTHRENE)RUTHENIUM(II) AND GUANOSINE-MONOPHOSPHATE - A MODEL FOR A NEW MODE OF COVALENT BINDING OF METAL-COMPLEXES TO DNA

Authors
JACQUET L KELLY JM DEMESMAEKER AK
Citation
L. Jacquet et al., PHOTOADDUCT BETWEEN TRIS(1,4,5,8-TETRAAZAPHENANTHRENE)RUTHENIUM(II) AND GUANOSINE-MONOPHOSPHATE - A MODEL FOR A NEW MODE OF COVALENT BINDING OF METAL-COMPLEXES TO DNA, Journal of the Chemical Society, Chemical Communications, (9), 1995, pp. 913-914
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1995
Pages
913 - 914
Database
ISI
SICI code
0022-4936(1995):9<913:PBTA>2.0.ZU;2-D
Abstract
Visible light irradiation of [Ru(TAP)(3)](2+) (TAP = 1,4,5,8-tetraazap henanthrene) in aqueous solutions containing 5'-guanosine-monophosphat e (GMP) and subsequent treatment with 1 mol dm(-3) HCl yields Ru(TAP)( 2)(2-TAP-G)(2+), in which the guanine moiety is bound via N-2 to C-2 o f one of the TAP ligands.