Tc. Lau et Ck. Mak, OXIDATION OF C-2, C-3 AND HIGHER ALKANES BY A RUTHENIUM OXO SYSTEM, Journal of the Chemical Society, Chemical Communications, (9), 1995, pp. 943-944
Barium ruthenate, BaRuO3(OH)(2), when dissolved in TFA-CH2Cl2 containi
ng a few equivalents of 2,2'-bipyridine, generates a highly reactive r
uthenium-oxo system that is capable of oxidizing ethane and propane at
room temperature with good yields.