REDUCTIVE CLEAVAGE AS A ROUTE TO CARBOHYDRATE ENOLATES - APPLICATIONSTO THE SYNTHESIS OF C-LINKED DISACCHARIDES

Authors
BINCH HM GRIFFIN AM SCHWIDETZKY S RAMSAY MVJ GALLAGHER T LICHTENTHALER FW
Citation
Hm. Binch et al., REDUCTIVE CLEAVAGE AS A ROUTE TO CARBOHYDRATE ENOLATES - APPLICATIONSTO THE SYNTHESIS OF C-LINKED DISACCHARIDES, Journal of the Chemical Society, Chemical Communications, (9), 1995, pp. 967-968
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1995
Pages
967 - 968
Database
ISI
SICI code
0022-4936(1995):9<967:RCAART>2.0.ZU;2-5
Abstract
The carbohydrate-derived alpha-bromo ketones 4 and 5 undergo reductive cleavage using either Zn-Cu or CeCl3-Nal and the resulting enolates a re trapped by carbohydrate-based aldehydes 6, 7 and 14 to give C-disac charide derivatives.