INTRAMOLECULAR CYCLIZATIONS OF ALPHA-STANNYL RADICALS TO ACYLSILANES - REGIOSPECIFIC SYNTHESES OF 5-MEMBERED CYCLIC SILYL ENOL ETHERS

Authors
TSAI YM CHANG SY
Citation
Ym. Tsai et Sy. Chang, INTRAMOLECULAR CYCLIZATIONS OF ALPHA-STANNYL RADICALS TO ACYLSILANES - REGIOSPECIFIC SYNTHESES OF 5-MEMBERED CYCLIC SILYL ENOL ETHERS, Journal of the Chemical Society, Chemical Communications, (9), 1995, pp. 981-982
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1995
Pages
981 - 982
Database
ISI
SICI code
0022-4936(1995):9<981:ICOART>2.0.ZU;2-0
Abstract
alpha-Stannyl radicals generated from acylsilanes 5, 13 and 14 cyclize to give good yields of cyclic silyl enol ethers after sequential cycl izations, radical Brook rearrangements and beta-scissions.