DERIVED ABSOLUTE RATE CONSTANTS FOR ADDITIONS OF AMBIPHILIC CARBENES TO ALKENES

Authors
MOSS RA GE CS WLOSTOWSKA J JANG EG JEFFERSON EA FAN H
Citation
Ra. Moss et al., DERIVED ABSOLUTE RATE CONSTANTS FOR ADDITIONS OF AMBIPHILIC CARBENES TO ALKENES, Tetrahedron letters, 36(18), 1995, pp. 3083-3086
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
18
Year of publication
1995
Pages
3083 - 3086
Database
ISI
SICI code
0040-4039(1995)36:18<3083:DARCFA>2.0.ZU;2-9
Abstract
Additions of methoxychlorocharbene and trifluoroethoxychlorocarbene to trans-butene occur with k(abs) similar to 330 and 10,000 M(-1)s(-1), respectively.