R. Beugelmans et al., PALLADIUM-CATALYZED REDUCTIVE DEPROTECTION OF ALLOC - TRANSPROTECTIONAND PEPTIDE-BOND FORMATION, Tetrahedron letters, 36(18), 1995, pp. 3129-3132
N-allyloxycarbonyl group could be efficiently removed using sodium bor
ohyride as hydride donnor in the presence of catalytic amount of palla
dium (0). The conditions were applied to chemoselective protecting gro
up transformation (transprotection) and peptide bond formation.