FERROCENE-SUBSTITUTED AMIDINATE DERIVATIVES - SYNTHESES AND CRYSTAL-STRUCTURES OF LITHIUM, IRON(II), AND COBALT(II) COMPLEXES

Authors
HAGADORN JR ARNOLD J
Citation
Jr. Hagadorn et J. Arnold, FERROCENE-SUBSTITUTED AMIDINATE DERIVATIVES - SYNTHESES AND CRYSTAL-STRUCTURES OF LITHIUM, IRON(II), AND COBALT(II) COMPLEXES, Inorganic chemistry, 36(2), 1997, pp. 132
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
2
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:2<132:FAD-SA>2.0.ZU;2-C
Abstract
The ferrocene-containing amidinate anion FcC(NCy)(2)](-) (Fc=ferroceny l) is obtained by the reaction of N,N'-dicyclohexylcarbodiimide with F cLi in THF/hexanes. The lithium derivative reacts with 1/2 equiv of Fe Cl2 or CoBr2 to afford the trimetallic derivatives [FcC(NCy)(2)](2)M . nE(t)2O. X-ray crystal structures of the Li, Fe(II), and Co(II) deriv atives are reported.