REACTIONS OF RHENIUM(V) OXO AND NITRIDO COMPLEXES WITH 1-PHENYL-2-(DIPHENYLPHOSPHINO)ETHANONE (P(DOLLAR)OVER-CAP-OH) - SYNTHESIS AND CRYSTAL-STRUCTURE OF REOCL(P(DOLLAR)OVER-CAP-O)(2) AND REN(PPH(3))(P(DOLLAR)OVER-CAP-O)(2)

Authors
CONNAC F LUCCHESE Y DARTIGUENAVE M BEAUCHAMP AL
Citation
F. Connac et al., REACTIONS OF RHENIUM(V) OXO AND NITRIDO COMPLEXES WITH 1-PHENYL-2-(DIPHENYLPHOSPHINO)ETHANONE (P(DOLLAR)OVER-CAP-OH) - SYNTHESIS AND CRYSTAL-STRUCTURE OF REOCL(P(DOLLAR)OVER-CAP-O)(2) AND REN(PPH(3))(P(DOLLAR)OVER-CAP-O)(2), Inorganic chemistry, 36(2), 1997, pp. 256
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
2
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:2<256:ROROAN>2.0.ZU;2-M
Abstract
Structurally related six-coordinated oxo ReOCl(PO)(2) and nitrido ReN( PPh(3))(PO)(2) complexes were synthesized. The bidentate PO- ligand fo rms oxo ReOCl(PO)(2) and nitrido ReN(PPh(3))(PO)(2) complexes containi ng quasi-isostructural ReO(PO)(2) and ReN(PO)(2) units. The Cl site in the oxo compound is occupied by PPh(3) in the nitride. PPh(3) is smoo thly displaced in solution by pyridine, 1-methylimidazole, and P(p-tol yl)(3) with retention of stereochemistry.