DIORGANOTIN(IV) DERIVATIVES OF TRIDENTATE DITHIOCARBAZONES - STRUCTURE DETERMINATION IN THE SOLID AND LIQUID-STATE

Authors
KNOLL S TSCHWATSCHAL F RISTAU T GELBRICH T BORSDORF R ZAHN G
Citation
S. Knoll et al., DIORGANOTIN(IV) DERIVATIVES OF TRIDENTATE DITHIOCARBAZONES - STRUCTURE DETERMINATION IN THE SOLID AND LIQUID-STATE, Zeitschrift fur anorganische und allgemeine Chemie, 623(1), 1997, pp. 141-146
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
1
Year of publication
1997
Pages
141 - 146
Database
ISI
SICI code
0044-2313(1997)623:1<141:DDOTD->2.0.ZU;2-3
Abstract
The tridentate ligands with the S-Methyldithiocarbazate Schiff Base of 2-Salicylaldehyde (H(2)Sal) and 2-Pyridinaldehyde (HPyr) react in dif ferent way with diorganotin(IV) oxides, in the first case to the five- coordinate complex R(2)Sn-Sal with trigonal bipyramidal structure and in the second case to the binuclear complex [(R(2)Sn-Pyr)(2)CO3] with a bridging carbonat anion. The structures were elucidated by X-ray dif fraction and by multinuclear NMR in solution. IR- and Mass-spectrometr ic measurements complete the results.