T. Hayashi et al., NANO-STRUCTURE FABRICATION BY USING SELF-ORGANIZING PROPERTIES OF MATERIALS, Journal of intelligent material systems and structures, 5(6), 1994, pp. 733-735
Self-organizing properties of materials can be used to fabricate well-
ordered nanostructures on a large scale and also to develop new advanc
ed materials. Three examples of self-organized nano-structures are des
cribed in this paper. A unidirectionally ordered metallophthalocyanine
thin film was formed over the entire surface of a sapphire (1 (1) ove
r bar 02) substrate by using a newly synthesized dibenzo[b,t] phthaloc
yaninato-Zn(II), which has a unique two-fold symmetrical molecular str
ucture. A buried SiO2, layer with atomically abrupt Si/SiO2, interface
was formed by oxygen ion implantation into silicon and subsequent ann
ealing. A nano-particle consisting of outer graphitic shells and a cor
e nano-crystal of LaC2 was formed in a self-organizing manner when a h
ot carbon-langhanum particle was cooled on an are-discharge electrode
in a He atmosphere.