We have been successful in imaging environmental aerosol particles by
atomic force microscopy (AFM). The material under investigation was ru
ral aerosol collected with an 11-stage low-pressure impactor. On polye
ster substrates, particles smaller than 20 mn could be observed. From
the AFM data, size distributions have been determined and compared wit
h the expected performance of the used cascade impactor. The mean part
icle sizes (aerodynamic equivalent diameter) were in good agreement wi
th the values derived from AFM experiments. Moreover, we have obtained
atomically resolved images on single aerosol particles; to our knowle
dge, this is the first time this has been accomplished on environmenta
l samples. AFM images of larger impactor stages showed good agreement
with light and electron microscopy micrographs.