BETA-CYCLODEXTRIN-MEDIATED STEREOREGULARITY IN POLYACRYLONITRILE POLYMERS

Authors
RAVI P DIVAKAR S
Citation
P. Ravi et S. Divakar, BETA-CYCLODEXTRIN-MEDIATED STEREOREGULARITY IN POLYACRYLONITRILE POLYMERS, Pure and applied chemistry, A32(5), 1995, pp. 1061-1066
Citations number
14
Categorie Soggetti
Polymer Sciences
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
A32
Issue
5
Year of publication
1995
Pages
1061 - 1066
Database
ISI
SICI code
0033-4545(1995)A32:5<1061:BSIPP>2.0.ZU;2-G
Abstract
Polyacrylonitrile polymers produced in the presence of molar equivalen ts of P-cyclodextrin (BCD) showed variation in stereoregularity. Thus, an increase in the acrylonitrile:BCD ratio showed an increase in isot acticity in the polymers formed. Inclusion complexation of acrylonitri le by BCD was detected by both H-1-NMR spectroscopy and UV-Vis spectro scopy, which gave a binding constant value of 7242 +/- 360 M(-1) for t he 1:1 complex.