Surface modifications of glass-reinforced hydroxyapatite composites im
mersed in a simulated physiological solution were studied using X-ray
photoelectron spectroscopy, scanning electron microscopy and energy di
spersive X-ray spectroscopy. In the first stages of the apatite format
ion process, calcium and silicon ions were leached out from the surfac
e of the composites. After 12 days of immersion, apatite crystals were
detected on the surface indicating bioactive behaviour. Sodium ions a
ttributed to sodium sulphate were also found in the apatite layer. Bou
nd water on the surface also increased with immersion time.