G. Galvagno et al., 2-DIMENSIONAL ALUMINUM DIFFUSION IN SILICON - EXPERIMENTAL RESULTS AND SIMULATIONS, Journal of the Electrochemical Society, 142(5), 1995, pp. 1585-1590
Two-dimensional diffusion of aluminum implanted through a mask in sili
con has been measured after furnace or rapid thermal annealings. Chemi
cal staining on cross-sectioned samples was used to determine both the
vertical and the lateral junction depths. The spreading resistance st
andard procedure was adopted to measure the vertical profiles while a
new procedure was developed for the determination of the lateral diffu
sion profiles. The difference in the measured profile by staining and
spreading resistance is related to the spilling phenomenon that distor
ts the carrier concentration profile on beveled samples. Moreover, exp
erimentally aluminum diffusion parameters and segregation coefficient
at the Si/SiO2 interface have been introduced in advanced one-dimensio
nal (SUPREM III) and two-dimensional (SUPREM IV) process simulators. T
he good agreement between the simulated and the experimental data, for
both the lateral and the vertical directions, indicates that these pr
ocess simulators can reproduce with accuracy the aluminum diffusion.